Pieces error: filestore error: chmod on FreeNAS (FreeBSD)

Seems you have used ACLs https://www.freebsd.org/doc/handbook/fs-acl.html
Please, set them to the full access or remove completely with

setfacl -kR /Storj/Storj-v3-data

For ref: https://forums.freebsd.org/threads/operation-not-permitted-when-chmod-with-root.73133/

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